The rates of population of the rovibrational levels of H-2 by the impa
ct of energetic photoelectrons produced by the absorption of X-rays ar
e calculated. Population occurs by excitation of electronically excite
d states of H-2 followed by cascading and by direct impact excitation
of the lowest vibrational level. The resulting infrared spectra are pr
esented. The emission from high vibrational levels is similar to that
from ultraviolet pumping. Emission from the v = 1 and 2 vibrational le
vels in a gas of low fractional ionization is dominated by direct elec
tron impact excitation. The intensity ratio of the S(1)(2-1) and S(1)(
1-0) lines is 0.06 in a gas of low fractional ionization and 0.54 in a
gas of high fractional ionization.