FORMATION OF CU(I)-NITRILE AND CU(II)-AMI NE MIXED-VALENCE COMPLEXES IN THE VINYLAMINE-ACRYLONITRILE COPOLYMER SYSTEM

Authors
SHIRAI H TAMURA A SUZUKI M KOYAMA T HANABUSA K KUROSE A SAWAYAMA S
Citation
H. Shirai et al., FORMATION OF CU(I)-NITRILE AND CU(II)-AMI NE MIXED-VALENCE COMPLEXES IN THE VINYLAMINE-ACRYLONITRILE COPOLYMER SYSTEM, Kobunshi ronbunshu, 54(1), 1997, pp. 45-51
Citations number
15
Categorie Soggetti
Polymer Sciences
Journal title
Kobunshi ronbunshu → ACNP
ISSN journal
03862186
Volume
54
Issue
1
Year of publication
1997
Pages
45 - 51
Database
ISI
SICI code
0386-2186(1997)54:1<45:FOCACN>2.0.ZU;2-2
Abstract
In earlier work, we reported on the complex formation of a vinylamine- acrylonitrile copolymer and Cu(II) ions in an aqueous solution. The Cu (II) ion formed a complex with vinylamine units, taking the Cu(II) (N- 4) planar structure. In addition, the Cu(I) ion formed a complex with acrylonitrile units. In this work, we observed the formation of a copo lymer-Cu(II)-Cu(I) mixed valence complex.