Je. Carsley et al., A SIMPLE, MIXTURES-BASED MODEL FOR THE GRAIN-SIZE DEPENDENCE OF STRENGTH IN NANOPHASE METALS, Nanostructured materials, 5(4), 1995, pp. 441-448
A model is presented for the strength of nanophase metals. The model a
ssumes that polycrystalline metals consist of two phases: the ''bulk''
intragranular regions, and the ''grain boundaries.'' The boundary pha
se is treated as a glassy, but not highly rare-dependent material with
a constant strength equal to that of the amorphous metal. The crystal
line phase is assumed to follow a Hall-Fetch equation for the grain-si
ze dependence of strength. Treating the material as a composite, with
a rule of mixtures approach, predicts a change in the Hall-Fetch slope
at small grain sizes, as has been observed. Grain size softening is p
redicted, but not until sizes below 5 nm. The model is compared to dat
a in the literature.