SILICON INSERTION INTO BORANES - A RATIONAL SYNTHETIC ROUTE TO SILICON-CONTAINING HETEROBORANES

Authors
DOPKE JA BRIDGES AN SCHMIDT MR GAINES DF
Citation
Ja. Dopke et al., SILICON INSERTION INTO BORANES - A RATIONAL SYNTHETIC ROUTE TO SILICON-CONTAINING HETEROBORANES, Inorganic chemistry, 35(25), 1996, pp. 7186
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
35
Issue
25
Year of publication
1996
Database
ISI
SICI code
0020-1669(1996)35:25<7186:SIIB-A>2.0.ZU;2-L
Abstract
The reactive dianion nido-B10H122- has been shown to insert silicon mo ieties to generate heteroundecaboranes of the form 7-R-7-SiB10H12-. NM R data for two new derivatives (R = H, Ph) are presented in addition t o a proposed mechanism of insertion.