Analysis from a number of different perspectives has shown diffusion a
nd dispersion in natural porous formations to generally be nonlocal in
character, i.e., the mass balance involves integro-partial differenti
al equations. Only in certain asymptotic limits do these laws localize
to classical partial differential equations. Compiled within is a res
ume of nonlocal laws that our group has developed over the last few ye
ars for systems with physical, chemical and biological heterogeneity.
Analytical tools used to obtain these laws are nonequilibrium and equi
librium statistical mechanics, and first-order spectral-perturbation m
ethods. This paper is an expansion of the material presented at the Wa
terloo conference held in the memory of Dr. Unny.