THE HETEROBIMETALLIC POLYMERIC ZIGZAG CHAIN [(W4S16AG4)(4-)](N) DERIVED FROM THE LINEAR-CHAIN [(WS4AG)(-)](N) - SYNTHESIS, CHARACTERIZATION, AND STRUCTURE OF [W4S16AG4.2CA(DMSO)(6)](N) (DMSO=DIMETHYL SULFOXIDE)
Q. Huang et al., THE HETEROBIMETALLIC POLYMERIC ZIGZAG CHAIN [(W4S16AG4)(4-)](N) DERIVED FROM THE LINEAR-CHAIN [(WS4AG)(-)](N) - SYNTHESIS, CHARACTERIZATION, AND STRUCTURE OF [W4S16AG4.2CA(DMSO)(6)](N) (DMSO=DIMETHYL SULFOXIDE), Inorganic chemistry, 35(25), 1996, pp. 7445
The novel heterobimetallic tungsten-silver-sulfur polymeric complex [W
4S16Ag4 .-2Ca(DMSO)(6)](n) has been synthesized from addition of Ca(II
) into a solution of the linear chain polymeric complex [WS4Ag . HNEt(
3) . DMF](n) in DMSO. The anionic structure of this complex can be vie
wed as a zigzag chain.