THE HETEROBIMETALLIC POLYMERIC ZIGZAG CHAIN [(W4S16AG4)(4-)](N) DERIVED FROM THE LINEAR-CHAIN [(WS4AG)(-)](N) - SYNTHESIS, CHARACTERIZATION, AND STRUCTURE OF [W4S16AG4.2CA(DMSO)(6)](N) (DMSO=DIMETHYL SULFOXIDE)

Authors
Citation
Q. Huang et al., THE HETEROBIMETALLIC POLYMERIC ZIGZAG CHAIN [(W4S16AG4)(4-)](N) DERIVED FROM THE LINEAR-CHAIN [(WS4AG)(-)](N) - SYNTHESIS, CHARACTERIZATION, AND STRUCTURE OF [W4S16AG4.2CA(DMSO)(6)](N) (DMSO=DIMETHYL SULFOXIDE), Inorganic chemistry, 35(25), 1996, pp. 7445
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00201669
Volume
35
Issue
25
Year of publication
1996
Database
ISI
SICI code
0020-1669(1996)35:25<7445:THPZC[>2.0.ZU;2-8
Abstract
The novel heterobimetallic tungsten-silver-sulfur polymeric complex [W 4S16Ag4 .-2Ca(DMSO)(6)](n) has been synthesized from addition of Ca(II ) into a solution of the linear chain polymeric complex [WS4Ag . HNEt( 3) . DMF](n) in DMSO. The anionic structure of this complex can be vie wed as a zigzag chain.