APPLICATIONS OF THE SHRIMP-I ION MICROPROBE TO THE UNDERSTANDING OF PROCESSES AND TIMING OF DIAMOND FORMATION

The ion microprobe is a highly versatile analytical instrument capable of a wide variety of in situ isotopic and trace element studies of so lid materials, with a spatial resolution of 15 to 25 mm, consuming onl y 2 to 5 ng of sample per determination. In a study combining uranium- lead isotope dating, rare earth element fingerprinting, and sulfur plu s lead isotope tracing, it has been possible to address critical quest ions concerning the timing of, sources of materials for, and processes involved in diamond formation in African kimberlites. The zircon uran ium-lead data indicate that kimberlites may host two generations of mi nerals: one crystallizing at the time of kimberlite emplacement and th e other significantly older, perhaps relict from a previous kimberlite magma-generating event. Rare earth element analyses of the same zirco ns suggest that the two generations of zircons are different from each other and both are quite distinct from crustal zircons. Since zircon is not a common phase in the mantle, it may be that some mantle metaso matic event is required to form these minerals and may actually trigge r kimberlite generation. The sulfur isotope data from sulfide inclusio ns in diamonds suggest that two different reservoirs are being sampled during diamond growth: one with essentially pristine mantle character istics and another with variability more reminiscent of a low-temperat ure or more oxidizing, possibly crustal, environment. Paragenetic data , based on nickel contents of the sulfides, indicate that it is the ec logitic diamonds which record the crustal signatures. Lead isotope var iability parallels that found in sulfur, with perdiotitic sulfides hav ing apparently normal mantle lead and eclogitic sulfides having much m ore radiogenic lead which in some cases requires very high U/Pb ratio growth environments, more consistent with a crustal source. The data f rom this study and others, including the carbon isotope heterogeneity of eclogitic diamonds, can be reconciled with a single model in which introduction of crustal material into the mantle triggers both generat ion of the kimberlite and diamond growth. This makes plate tectonics o f paramount importance in locating economic reserves of diamonds.