DESIGN OF FERROMAGNETIC POLYMERS INVOLVING ORGANOSILICON MOIETIES

Authors
TANAKA K AGO H YAMABE T
Citation
K. Tanaka et al., DESIGN OF FERROMAGNETIC POLYMERS INVOLVING ORGANOSILICON MOIETIES, Synthetic metals, 72(3), 1995, pp. 225-229
Citations number
27
Categorie Soggetti
Physics, Condensed Matter","Metallurgy & Metallurigical Engineering
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
72
Issue
3
Year of publication
1995
Pages
225 - 229
Database
ISI
SICI code
0379-6779(1995)72:3<225:DOFPIO>2.0.ZU;2-I
Abstract
Polaronic ferromagnetic polymers consisting of the spin supplier block (SSB) and the spacer have been designed based on the unrestricted Har tree-Fock (UHF) crystal orbital (CO) method. The pi-conjugated thienyl ene unit was employed as the SSB and the silylene or ethylene group wi th sp(3)-hybridized orbitals was taken as the spacer. Several kinds of combinations of these 'parts' were examined for the choice toward pro mising ferromagnetic polymers.