SYNTHESIS AND PROPERTIES OF BRIDGED PHTHALOCYANINATOIRON(II) COMPLEXES WITH BIDENTATE ALIPHATIC ISOCYANIDES

Authors
RYU H KNECHT S SUBRAMANIAN LR HANACK M
Citation
H. Ryu et al., SYNTHESIS AND PROPERTIES OF BRIDGED PHTHALOCYANINATOIRON(II) COMPLEXES WITH BIDENTATE ALIPHATIC ISOCYANIDES, Synthetic metals, 72(3), 1995, pp. 289-296
Citations number
44
Categorie Soggetti
Physics, Condensed Matter","Metallurgy & Metallurigical Engineering
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
72
Issue
3
Year of publication
1995
Pages
289 - 296
Database
ISI
SICI code
0379-6779(1995)72:3<289:SAPOBP>2.0.ZU;2-K
Abstract
Phthalocyaninatoiron(II) (PcFe) was reacted with several aliphatic 5, 10-13, alicyclic 14, and aromatic isocyanides 3, 4 to form monomeric 1 5-17 and bridged oligomeric complexes 18-22. The syntheses of the isoc yanides from the corresponding amines are described. All the products were characterized by spectroscopic methods. The coordination behaviou r of the isocyanides based on their spectroscopic properties is discus sed. The oligomers 18-22 show conductivities in the low semiconducting region, but by doping with iodine conductivities between 10(-5) and 1 0(-2) S/cm were obtained.