REGIOSELECTIVE OLEFIN HYDROFORMYLATION AS A ROUTE TO INDOLIZIDINE ANDPYRROLIZIDINE

Authors
CUNY GD BUCHWALD SL
Citation
Gd. Cuny et Sl. Buchwald, REGIOSELECTIVE OLEFIN HYDROFORMYLATION AS A ROUTE TO INDOLIZIDINE ANDPYRROLIZIDINE, Synlett, (5), 1995, pp. 519-522
Citations number
58
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
5
Year of publication
1995
Pages
519 - 522
Database
ISI
SICI code
0936-5214(1995):5<519:ROHAAR>2.0.ZU;2-F
Abstract
Regioselective, rhodium-catalyzed hydroformylation of olefinic pyrroli dine derivatives was utilized as a key step in the formal syntheses of the indolizidine alkaloids (+/-)-167B, 2, and (+/-)-209D, 3, and the ant venom pyrrolizidine alkaloid (3S,5R,8S)-3-heptyl-5-methylpyrrolizi dine, 4.