D. Martinvosshage et Bvr. Chowdari, X-RAY PHOTOELECTRON-SPECTROSCOPY STUDIES ON PEO(N)MBR(2) (M=CO, NI, ZN) SOLID ELECTROLYTES, Solid state ionics, 78(1-2), 1995, pp. 9-17
PEO(n)MBr(2) (M=Co, Ni, Zn) electrolytes were prepared at room tempera
ture with values of n ranging from 128 to 8. X-ray photoelectron spect
roscopy studies for each electrolyte system indicate a characteristic
interaction of the -CH2-CH2-O-chain of PEO with the divalent cations.
While in PEO there is only one kind of carbon, these interactions have
led to the formation of inequivalent carbons in all three electrolyte
systems with increased salt concentration. Strongest cation interacti
on is identified for all systems at a salt concentration corresponding
to n congruent to 16. Whereas the cations are found to change their c
oordination with varying salt concentration, the anions of each system
are found to have nearly unchanged coordination. These results reveal
the PEG(n)MBr(2) systems with M=Co, Ni and Zn as complexes formed by
the ether oxygen of PEO and each cation and an effective cross-linking
between the -CH2-CH2-O-chain and the anion of the salt.