ANILINE POLYMERIZATION IN HUP-LIKE FRAMEWORKS

Authors
COLOMBAN P EFREMOVA A GRUGER A NOVAK A
Citation
P. Colomban et al., ANILINE POLYMERIZATION IN HUP-LIKE FRAMEWORKS, Solid state ionics, 78(1-2), 1995, pp. 19-30
Citations number
27
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical
Journal title
Solid state ionics → ACNP
ISSN journal
01672738
Volume
78
Issue
1-2
Year of publication
1995
Pages
19 - 30
Database
ISI
SICI code
0167-2738(1995)78:1-2<19:APIHF>2.0.ZU;2-J
Abstract
The aniline intercalation in chemically dehydrated H3OUO2PO4.3H(2)O (H UP) and H5O2Fe(SO4)(2).2H(2)O(HFe), its protonation and the formation of oligomers and/or conducting polymers by CuCl contact have been stud ied by IR absorption, Raman scattering, X ray diffraction, and frequen cy dependent conductivity. The role of the atmosphere of handling and of the protons of the host framework are studied. A discussion of the polymerization mechanism is given.