K. Ehrensberger et al., COMPARATIVE EXPERIMENTAL INVESTIGATIONS OF THE WATER-SPLITTING REACTION WITH IRON-OXIDE FE1-YO AND IRON-MANGANESE OXIDES (FE1-XMNX)(1-Y)O, Solid state ionics, 78(1-2), 1995, pp. 151-160
The oxidation of the non-stoichiometric iron oxide Fe1-yO and mixed ir
on manganese oxides (Fe1-xMnx)(1-y)O (x less than or equal to 0.3) by
water forms molecular hydrogen. The course of this reaction was studie
d in a tubular fixed bed reactor at various temperatures by means of o
n-line mass spectrometry of the gas phase and by structural investigat
ions of the solid products with powder X-ray diffraction and scanning
electron microscopy.