Ps. Anderson, MECHANISM FOR THE BEHAVIOR OF HYDROACTIVE MATERIALS USED IN HUMIDITY SENSORS, Journal of atmospheric and oceanic technology, 12(3), 1995, pp. 662-667
The theory of operation of humidity sensors has not been widely discus
sed in the literature. In particular, no convincing explanation has be
en given as to why they respond to relative humidity (RH) rather than
to an absolute measure of humidity, such as vapor pressure or mixing r
atio, over a wide temperature range. A simple mechanism based on the a
dhesion of surface water to polarized solids is presented that explain
s many of the properties of these sensors.