POTASSIUM FLUORIDE ON ALUMINA - ONE-POT SYNTHESIS OF ALLYL DITHIOESTERS BY TANDEM CONDENSATION-ALKYLATION-SIGMATROPIC REARRANGEMENT

Authors
VILLEMIN D HACHEMI M
Citation
D. Villemin et M. Hachemi, POTASSIUM FLUORIDE ON ALUMINA - ONE-POT SYNTHESIS OF ALLYL DITHIOESTERS BY TANDEM CONDENSATION-ALKYLATION-SIGMATROPIC REARRANGEMENT, Synthetic communications, 25(15), 1995, pp. 2305-2310
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
25
Issue
15
Year of publication
1995
Pages
2305 - 2310
Database
ISI
SICI code
0039-7911(1995)25:15<2305:PFOA-O>2.0.ZU;2-7
Abstract
alpha-Methylene ketones adsorbed on KF-alumina at room temperature rea ct quickly with carbon disulfide and two equivalents of allyl chloride . The products undergo sigmatropic rearrangement, to give the correspo nding allyl ketodithioesters.