D. Villemin et M. Hachemi, POTASSIUM FLUORIDE ON ALUMINA - ONE-POT SYNTHESIS OF S-ALLYL-S-METHYLDITHIOCARBONATES BY TANDEM CONDENSATION-ALKYLATION-SIGMATROPIC REARRANGEMENT, Synthetic communications, 25(15), 1995, pp. 2311-2318
Allyl alcohols adsorbed on Al2O3-KF at room temperature reacted with c
arbon disulfide and iodomethane and gave S-allyl-S-methyldithiocarbona
te. Linalool did not give a rearrangement product. With chrysanthemyl
alcohol, opening of the cyclopropane ring was observed.