POTASSIUM FLUORIDE ON ALUMINA - ONE-POT SYNTHESIS OF S-ALLYL-S-METHYLDITHIOCARBONATES BY TANDEM CONDENSATION-ALKYLATION-SIGMATROPIC REARRANGEMENT

Citation
D. Villemin et M. Hachemi, POTASSIUM FLUORIDE ON ALUMINA - ONE-POT SYNTHESIS OF S-ALLYL-S-METHYLDITHIOCARBONATES BY TANDEM CONDENSATION-ALKYLATION-SIGMATROPIC REARRANGEMENT, Synthetic communications, 25(15), 1995, pp. 2311-2318
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00397911
Volume
25
Issue
15
Year of publication
1995
Pages
2311 - 2318
Database
ISI
SICI code
0039-7911(1995)25:15<2311:PFOA-O>2.0.ZU;2-8
Abstract
Allyl alcohols adsorbed on Al2O3-KF at room temperature reacted with c arbon disulfide and iodomethane and gave S-allyl-S-methyldithiocarbona te. Linalool did not give a rearrangement product. With chrysanthemyl alcohol, opening of the cyclopropane ring was observed.