2-(P-DIMETHYLAMINOPHENYL)INDAN-1,3-DIONE-2-YL RADICAL - ENDOR AND ESRSTUDIES AND MNDO CALCULATION

Authors
MOTYAKIN MV PISARENKO LM SCHULER P STEGMANN HB
Citation
Mv. Motyakin et al., 2-(P-DIMETHYLAMINOPHENYL)INDAN-1,3-DIONE-2-YL RADICAL - ENDOR AND ESRSTUDIES AND MNDO CALCULATION, Magnetic resonance in chemistry, 33(6), 1995, pp. 471-475
Citations number
14
Categorie Soggetti
Spectroscopy,Chemistry
Journal title
Magnetic resonance in chemistry → ACNP
ISSN journal
07491581
Volume
33
Issue
6
Year of publication
1995
Pages
471 - 475
Database
ISI
SICI code
0749-1581(1995)33:6<471:2R-EAE>2.0.ZU;2-4
Abstract
ENDOR and ESR spectra of the 2-(p-dimethylaminophyenyl)indan-1-,3-dion e-2-yl radical were measured in toluene and diethyl phthalate at 350 K . A solvent dependence of the coupling constants was observed. Using t he MNDO method, the optimized structure of the radical and the spin po pulation distribution were derived.