COCRYSTALLIZATION OF CU2+ WITH NH4CL BY THE ANOMALOUS ISOMORPHISM MECHANISM

Authors
PLATONOVA NV PUNIN YO FRANKE VD KOTELNIKOVA EN
Citation
Nv. Platonova et al., COCRYSTALLIZATION OF CU2+ WITH NH4CL BY THE ANOMALOUS ISOMORPHISM MECHANISM, Journal of structural chemistry, 35(5), 1994, pp. 634-641
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of structural chemistry → ACNP
ISSN journal
00224766
Volume
35
Issue
5
Year of publication
1994
Pages
634 - 641
Database
ISI
SICI code
0022-4766(1994)35:5<634:COCWNB>2.0.ZU;2-C
Abstract
In the ammonium chloride crystallization region of the NH4Cl-CuCl2-H2O -CH3ON system, cocrystallization of the impurity with the main substan ce occurs by epitaxial adsorption of complexes of varying composition. In NH4Cl crystals, the Cu2+ impurity forms oriented interlayers (ingr owths) simultaneously at the macro- and microlevels. The ratio between the two trapping forms depends on the growth conditions.