COMBINATION OF IONIC AND METAL-OLEFIN BONDS IN CRYSTALLINE COPPER(I) PI-COMPLEXES

Authors
OLIJNIK VV GORESHNIK EA
Citation
Vv. Olijnik et Ea. Goreshnik, COMBINATION OF IONIC AND METAL-OLEFIN BONDS IN CRYSTALLINE COPPER(I) PI-COMPLEXES, Journal of structural chemistry, 35(5), 1994, pp. 668-676
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of structural chemistry → ACNP
ISSN journal
00224766
Volume
35
Issue
5
Year of publication
1994
Pages
668 - 676
Database
ISI
SICI code
0022-4766(1994)35:5<668:COIAMB>2.0.ZU;2-N
Abstract
The ionic field effect on metal-olefin pi-binding is considered for 24 Cu(I) compound; based on X-ray diffraction data. Structural features due to Cu...(C=C)-H...An and N-H...An bridges in cationic and zwitteri onic pi-complexes, respectively are discussed. Parity of metal-olefin and hydrogen bonds in formation of these structures is shown.