ABSOLUTE-CONFIGURATION AND GROWTH OF THE POTASSIUM BIPHTHALATE CRYSTAL (C6H4)COOH-CENTER-DOT-COOK

Citation
Ng. Furmanova et al., ABSOLUTE-CONFIGURATION AND GROWTH OF THE POTASSIUM BIPHTHALATE CRYSTAL (C6H4)COOH-CENTER-DOT-COOK, Journal of structural chemistry, 35(5), 1994, pp. 697-701
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
ISSN journal
00224766
Volume
35
Issue
5
Year of publication
1994
Pages
697 - 701
Database
ISI
SICI code
0022-4766(1994)35:5<697:AAGOTP>2.0.ZU;2-7
Abstract
The direction of the polar axis of the potassium biphthalate (KAP) cry stal was determined by anomalous X-ray scattering (lambda Cu). Accordi ng to the etching pattern on the same sample, the positive direction o f the axis corresponds to the slow-growing end of the crystal. Crystal chemical features of the main faces of the KAP crystal ({111} and {11 (1) over bar} pyramids, {010} pinacoid, and {110} prism) were revealed . This allowed us to explain the anisotropy of impurity (ethylene glyc ol, di- or trivalent metal cations) effects on the growth of separate faces of the crystal.