AN UNUSUALLY FACILE [3,3]-SIGMATROPIC REARRANGEMENT IN A STEREOSPECIFIC SYNTHESIS OF NOVEL 2',3'-DIDEOXYNUCLEOSIDE PRECURSORS

Authors
ARMSTRONG PL COULL IC HEWSON AT SLATER MJ
Citation
Pl. Armstrong et al., AN UNUSUALLY FACILE [3,3]-SIGMATROPIC REARRANGEMENT IN A STEREOSPECIFIC SYNTHESIS OF NOVEL 2',3'-DIDEOXYNUCLEOSIDE PRECURSORS, Tetrahedron letters, 36(24), 1995, pp. 4311-4314
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
24
Year of publication
1995
Pages
4311 - 4314
Database
ISI
SICI code
0040-4039(1995)36:24<4311:AUF[RI>2.0.ZU;2-T
Abstract
The glycal 5 is converted to intermediates which undergo, under mild c onditions, thermal aza-Claisen rearrangements, leading to tile amides 7 and 8 and the 2-pyrimidone 9, all potential precursors to 2',3'-dide oxynucleosides.