Ya. Mankelevich et al., 2-DIMENSIONAL MODEL OF REACTIVE GAS-FLOW IN A DIAMOND FILM CVD-REACTOR, DIAMOND AND RELATED MATERIALS, 4(8), 1995, pp. 1065-1068
A two-dimensional model of the reactive gas flow, heat transfer and el
ectrodynamic phenomena in a d.c. discharge reactor for diamond film de
position has been developed. Contrary to earlier proposed models we ca
lculate the electron-molecule reaction rate coefficients by solving th
e Boltzmann equation for the electron energy distribution function. Th
ese coefficients are used for chemical gas composition calculations. A
n effective numerical method for solving the chemical kinetics equatio
ns has been developed. The electric field strength was determined from
the total current conservation condition and the electron balance equ
ation. The spatial distributions and fluxes of the chemical species an
d the gas flow parameters have been obtained as a result of the self-c
onsistent calculations.