We report the results of a survey at very high spectral resolution of
interstellar CH and CH+ in diffuse clouds toward 20 bright stars, and
medium-resolution observations to determine radial velocities. The hig
h-resolution observations [(lambda/delta lambda) similar to 500,000] r
esolve all the CH+ and all the CH lines. Most of the CH lines show mul
tiple overlapping components at this resolution. It is often possible
to associate a weak broad CH component with a CH+ component of similar
radial velocity and width. The implications of these results for CH a
nd CH+ formation scenarios are discussed.