LAYERED STRUCTURE OF ERB-1 MICROPOROUS BOROSILICATE PRECURSOR AND ITSINTERCALATION PROPERTIES TOWARDS POLAR-MOLECULES

Authors
MILLINI R PEREGO G PARKER WO BELLUSSI G CARLUCCIO L
Citation
R. Millini et al., LAYERED STRUCTURE OF ERB-1 MICROPOROUS BOROSILICATE PRECURSOR AND ITSINTERCALATION PROPERTIES TOWARDS POLAR-MOLECULES, Microporous materials, 4(2-3), 1995, pp. 221-230
Citations number
15
Categorie Soggetti
Chemistry Physical","Material Science","Chemistry Applied
Journal title
Microporous materials → ACNP
ISSN journal
09276513
Volume
4
Issue
2-3
Year of publication
1995
Pages
221 - 230
Database
ISI
SICI code
0927-6513(1995)4:2-3<221:LSOEMB>2.0.ZU;2-P
Abstract
As-synthesized ERB-1 borosilicate has a bi-dimensional layered structu re, and the three-dimensional (3D) microporous structure is formed aft er calcination at 270 degrees C. X-Ray powder diffraction (XRD), tempe rature-programmed desorption (TPD) and Si-29 magic-angle spinning nucl ear magnetic resonance (MAS NMR) analyses demonstrated that the format ion of the 3D ordered structure occurs through the condensation of sil anol groups present on the surfaces of the layers. As-synthesized ERB- 1 displays intercalation properties towards polar molecules such as et hylene glycol, isopropanol and [2,2,2]-azabicyclooctane.