(ETA(6)-POLYARENE)MN(CO)3(- A CONVENIENT AND GENERAL SYNTHETIC ROUTE TO (ARENE)MN(CO)3(+) COMPLEXES() COMPLEXES AS MANGANESE TRICARBONYL TRANSFER REAGENTS )
Sh. Sun et al., (ETA(6)-POLYARENE)MN(CO)3(- A CONVENIENT AND GENERAL SYNTHETIC ROUTE TO (ARENE)MN(CO)3(+) COMPLEXES() COMPLEXES AS MANGANESE TRICARBONYL TRANSFER REAGENTS ), Organometallics, 14(6), 1995, pp. 2613-2615
(Polyarene)Mn(CO)(3+) complexes containing naphthalene-type ligands ca
n be readily synthesized in high yield. These complexes function as ef
ficient manganese tricarbonyl transfer (MTT) reagents by rapidly and c
leanly transferring the Mn(CO)(3+) moiety to other arenes upon warming
in dichloromethane.