OXIDATIVE TRANSFORMATIONS OF ALDAZINES AND KETAZINES WITH ORGANIC PEROXYACIDS

Authors
MLOCHOWSKI J GIURG M
Citation
J. Mlochowski et M. Giurg, OXIDATIVE TRANSFORMATIONS OF ALDAZINES AND KETAZINES WITH ORGANIC PEROXYACIDS, Polish Journal of Chemistry, 68(11), 1994, pp. 2333-2342
Citations number
26
Categorie Soggetti
Chemistry
Journal title
Polish Journal of Chemistry → ACNP
ISSN journal
01375083
Volume
68
Issue
11
Year of publication
1994
Pages
2333 - 2342
Database
ISI
SICI code
0137-5083(1994)68:11<2333:OTOAAK>2.0.ZU;2-T
Abstract
Oxidation of aromatic aldazines and ketazines with various peroxycarbo xylic acids was investigated. It was found that one part of azine mole cule 2 was converted into carbonyl compound 1 or related acid 3 while the second part was transformed into carboxylic ester 4 related to per oxyacid used as an oxidant. It was revealed that aromatic azines could be used as a source of diazaarylmethanes and mechanisms of reactions studied were postulated.