C. Legressus et G. Blaise, CORRELATION OF INSULATOR PROPERTIES WITH ELECTRON SPECTROSCOPIC OBSERVATIONS, Analytica chimica acta, 297(1-2), 1994, pp. 139-152
Research of correlations between insulator macroscopic properties (ele
ctric strength, mechanical toughness, friction, radiation damage sensi
tivity, etc.) has shown that parameters related to polarization and en
ergy dissipation processes are relevant for these properties. The inve
stigation of the charging effect under an ionizing beam could be a way
of characterizing polarization and relaxation processes leading to br
eakdown, fracture, etc. The physical basis which allows to understand
the degree of insulator charging phenomena is reviewed. A universal co
ncept of trapping as well as the nature of the energy which is stored
in a charged dielectric are recalled. Basic principles of charging and
detrapping were verified on well defined materials. It was observed t
hat the relaxation of the mechanical energy consecutive to an abrupt v
ariation of the polarization is a major cause of defect generation lea
ding to failures. Results achieved by electron spectroscopy are review
ed. It is shown that there exist spectroscopic observations which can
be related to parameters governing electric and mechanical strengths.