Me. Zvanut et al., IDENTIFICATION OF PHOSPHORUS IN DIAMOND THIN-FILMS USING ELECTRON-PARAMAGNETIC-RESONANCE SPECTROSCOPY, Applied physics letters, 65(18), 1994, pp. 2287-2289
An electron paramagnetic-resonance study of diamond films doped by imp
lantation of phosphorus during film deposition is reported. Samples wi
th nominal phosphorus concentration between 10(16) and 10(17) cm(-3) e
xhibit two isotropic lines of equal intensity separated by 27 G. The d
ouble-line spectrum is expected for a nuclear-spin 1/2 species such as
phosphorus. The symmetry of the center and the temperature dependence
of the spin concentration suggest that phosphorus forms a substitutio
nal shallow donor in diamond. (c) 1994 American institute of Physics.