NOVEL COUPLING BETWEEN TRICARBONYL(7-AZABENZONORBORNADIENE)IRON COMPLEXES AND CYCLOHEXENE TO FORM STEREOSPECIFICALLY A (C-5 SUBSTITUTED ETA(4)-CYCLOHEXADIENE)FE(CO)(3) MOIETY

Authors
SUN CH SHANG NC LIEU LS WANG JC
Citation
Ch. Sun et al., NOVEL COUPLING BETWEEN TRICARBONYL(7-AZABENZONORBORNADIENE)IRON COMPLEXES AND CYCLOHEXENE TO FORM STEREOSPECIFICALLY A (C-5 SUBSTITUTED ETA(4)-CYCLOHEXADIENE)FE(CO)(3) MOIETY, Journal of organometallic chemistry, 481(2), 1994, pp. 179-181
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
481
Issue
2
Year of publication
1994
Pages
179 - 181
Database
ISI
SICI code
0022-328X(1994)481:2<179:NCBTC>2.0.ZU;2-M
Abstract
Novel coupling between tricarbonyl(7-azabenzonorbornadiene)iron comple xes 1 and cyclohexene occurs thermally and photochemically. Complexes 2 were formed stereospecifically with a yield of 21-34% via C-C bond f ormation from the exo-face of 7-ABND accompanied by the generation of ((4) eta-cyclohexadiene)Fe(CO)(3) moieties with Fe(CO)(3) syn to the n ew C-C bond. At the same time, C-5 of this moiety was functionalized w ith a bulky 7-ABND heterocycle.