SYNTHESIS OF TITANIUM SILICATE ETS-10 - THE EFFECT OF TETRAMETHYLAMMONIUM ON THE CRYSTALLIZATION KINETICS

Authors
VALTCHEV V MINTOVA S
Citation
V. Valtchev et S. Mintova, SYNTHESIS OF TITANIUM SILICATE ETS-10 - THE EFFECT OF TETRAMETHYLAMMONIUM ON THE CRYSTALLIZATION KINETICS, Zeolites, 14(8), 1994, pp. 697-700
Citations number
11
Categorie Soggetti
Chemistry Physical
Journal title
Zeolites → ACNP
ISSN journal
01442449
Volume
14
Issue
8
Year of publication
1994
Pages
697 - 700
Database
ISI
SICI code
0144-2449(1994)14:8<697:SOTSE->2.0.ZU;2-K
Abstract
Titanium silicate ETS-10 was synthesized from titanosilicate gels in t he presence of an organic template-tetrametylammonium (TMA) chloride-a t temperatures of 160, 180, and 200-degrees-C. The kinetic analysis of the crystallization of ETS-10 permits us to follow the role of the us ed template during the consecutive steps of the process. The presence of TMA diminishes the nucleation time and acclerates the crystal growt h. The incorporation of TMA in the channel system of titanium silicate changes significantly the crystal morphology of ETS-10.