PHOTOEMISSION FROM GASEOUS AND CONDENSED MOLECULAR CARBORANE CLUSTER MOLECULES

Authors
BYUN D LEE S HWANG SD HU YF BANCROFT GM GLASS JA ZHANG JD SPENCER JT MA J DOWBEN PA
Citation
D. Byun et al., PHOTOEMISSION FROM GASEOUS AND CONDENSED MOLECULAR CARBORANE CLUSTER MOLECULES, Journal of electron spectroscopy and related phenomena, 69(2), 1994, pp. 111-116
Citations number
25
Categorie Soggetti
Spectroscopy
Journal title
Journal of electron spectroscopy and related phenomena → ACNP
ISSN journal
03682048
Volume
69
Issue
2
Year of publication
1994
Pages
111 - 116
Database
ISI
SICI code
0368-2048(1994)69:2<111:PFGACM>2.0.ZU;2-J
Abstract
The electronic structure of the nido-2,3-R2-2,3-dicarbahexaborane (R2C 2B4H6) where R is C2H5) and closo-1,2-dicarbadodecaborane (C2B10H12) h ave been studied by photoemission spectroscopy (PES). Photoemission sp ectra for condensed nido-2,3-diethyl-2,3-dicarbahexaborane(8) ((C2H5)2 C2B4H6) exhibited features in good agreement with molecular orbitals a ssigned by modified neglect of differential overlap (MNDO) semiempiric al theoretical calculations. Similar agreement can be demonstrated for the closo-1,2-dicarbadodecaborane.