COEXISTING DENSITIES AND VAPOR-PRESSURES FOR R143 FROM 314-K TO 401-KWITH NEW CRITICAL-POINT PROPERTY ESTIMATES

Citation
Cd. Holcomb et Lj. Vanpoolen, COEXISTING DENSITIES AND VAPOR-PRESSURES FOR R143 FROM 314-K TO 401-KWITH NEW CRITICAL-POINT PROPERTY ESTIMATES, Fluid phase equilibria, 100, 1994, pp. 223-239
Citations number
18
Categorie Soggetti
Engineering, Chemical","Chemistry Physical
Journal title
ISSN journal
03783812
Volume
100
Year of publication
1994
Pages
223 - 239
Database
ISI
SICI code
0378-3812(1994)100:<223:CDAVFR>2.0.ZU;2-L
Abstract
The coexisting densities and vapor pressures of R143 (1,1,2-trifluoroe thane) have been measured at NIST from 314 to 401 K. These results wer e compared with available R143 data. The critical point was not determ ined experimentally because of the temperature limitations of the appa ratus. However, a revised estimate of the critical point based on the new experimental data was obtained by combining a new method of critic al temperature estimation with a previously reported method of critica l density determination. These data and the data of others were repres ented by both the Carnahan-Starling-DeSantis equation of state and the Deiters equation of state. The Carnahan-Starling-DeSantis equation of state better represented the data and is easier to use for the calcul ation of the thermodynamic properties of R143.