T. Kokubun et Jb. Harborne, A SURVEY OF PHYTOALEXIN INDUCTION IN LEAVES OF THE ROSACEAE BY COPPERIONS, Zeitschrift fur Naturforschung. C, A journal of biosciences, 49(9-10), 1994, pp. 628-634
The leaves of 130 species of Rosaceae were surveyed for phytoalexin in
duction. Both biotic and abiotic induction was examined and antifungal
compounds were detected in 47 species. However. these compounds appea
red to be constitutive metabolites, released from bound phenolic mater
ials already present in the leaf. In Pyrus, hydroquinone was produced
from the hydrolysis of arbutin present in the vacuole before inoculati
on. In most other species, the fungitoxic agents were mainly catechin-
like derivatives, apparently released from the tannins present within
the leaf. By contrast, the synthesis in the leaf of the characteristic
biphenyl or benzofuran phytoalexins which are produced in sapwood, wa
s confined to a very few species. The biphenyl aucuparin was identifie
d as a phytoalexin from the leaves of Sorbus aucuparia.