GENERALIZED RATE THEORY FOR SPATIALLY INHOMOGENEOUS SYSTEMS OF POINT-DEFECT SINKS

A statistical approach to the derivation of rate equations governing t he diffusion of point defects to a dilute random system of sinks in a homogeneous matrix is proposed and discussed. The approach clearly rev eals a hierarchical nature of the rate theory. A procedure allowing to reduce this hierarchy to the conventional set of rate equations and t o introduce self-consistently the concept of sink strength is describe d in detail. The resulting set of equations can be quite naturally app lied to spatially inhomogeneous sink systems, since the usual assumpti on of homogeneous sink distribution in the matrix is shown to be uness ential for the reduction procedure. Finally, the consecutive procedure for calculation of corrections to sink strength due to close sink con figurations is proposed and generalization of the rate theory in order to account for effects of elastic point defect interaction with sinks is discussed.