SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [ET(4)N][CO(NH2-CSNHNH2)(3)][MO8O26].4ME(2)NCHO

Authors
ZHANG HB NIU SY YANG GD NIE F LI SJ
Citation
Hb. Zhang et al., SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [ET(4)N][CO(NH2-CSNHNH2)(3)][MO8O26].4ME(2)NCHO, Transition metal chemistry, 19(5), 1994, pp. 498-502
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
19
Issue
5
Year of publication
1994
Pages
498 - 502
Database
ISI
SICI code
0340-4285(1994)19:5<498:SAXCO[>2.0.ZU;2-C
Abstract
[Et(2)N][Co(NH2CSNHNH2)(3)][Mo8O26].4Me(2)NCHO, obtained by reacting M oCl5, CoCl2, thiosemicarbazide and DMF in nonaqueous solvents under i. r. radiation, was characterized by spectroscopy and X-ray crystallogra phy. It contains an octanuclear molydenum anion with two pentabridging oxygen atoms and a cobalt-centred cation bonded to nitrogen and sulph ur ligands.