MONONUCLEAR MANGANESE(III) AQUO COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURES OF [MN(PHEN)(OH2)CL-3] AND [MN(ACAC)(2)-(OH2)(2)]CLO4-CENTER-DOT-2H2O (ACACH=ACETYLACETONE, PHEN=1,10-PHENANTHROLINE)

Authors
SWARNABALA G REDDY KR TIRUNAGAR J RAJASEKHARAN MV
Citation
G. Swarnabala et al., MONONUCLEAR MANGANESE(III) AQUO COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURES OF [MN(PHEN)(OH2)CL-3] AND [MN(ACAC)(2)-(OH2)(2)]CLO4-CENTER-DOT-2H2O (ACACH=ACETYLACETONE, PHEN=1,10-PHENANTHROLINE), Transition metal chemistry, 19(5), 1994, pp. 506-508
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
19
Issue
5
Year of publication
1994
Pages
506 - 508
Database
ISI
SICI code
0340-4285(1994)19:5<506:MMAC-C>2.0.ZU;2-M
Abstract
The crystal and molecular structures of [Mn(phen)(OH2)Cl-3] (1) and [M n(acac)(2)(OH2)(2)]ClO4.2H(2)O (2) were determined. A comparison is ma de of the Jahn-Teller distortion in these compounds with those observe d in other manganese(III) complexes with monodentate axial ligands.