SYNTHESIS OF OXAZOLYLINDOLYL ALKALOIDS VIA RHODIUM CARBENOIDS

Authors
DOYLE KJ MOODY CJ
Citation
Kj. Doyle et Cj. Moody, SYNTHESIS OF OXAZOLYLINDOLYL ALKALOIDS VIA RHODIUM CARBENOIDS, Synthesis, (10), 1994, pp. 1021
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
10
Year of publication
1994
Database
ISI
SICI code
0039-7881(1994):10<1021:SOOAVR>2.0.ZU;2-N
Abstract
The oxazolylindole alkaloids pimprinine (1a), pimprinethine (1b) and W S-30581 A (1c) are readily obtained in two steps by rhodium(II) cataly sed reaction of N-Boc-3-diazoacetylindole with the appropriate nitrile followed by removal of the Boc-group.