Enzyme-aided, totally chlorine-free bleaching of different industrial
softwood kraft pulps was studied using purified Trichoderma reesei xyl
anase and mannanase. Both xylanase and mannanase treatments were found
to increase the bleachability of the pulps, depending on the cooking
method used in pulp production. The effect of xylanase treatment on br
ightness was highest in the conventional kraft pulps and in pulps prod
uced by extended cooking methods. Higher amounts of lignin with higher
average molecular mass also could be extracted from these pulps after
xylanase treatment. The enzymes were especially effective in improvin
g the bleachability of oxygen-delignified pulps.