A new method was used to fabricate nanometer-scale structures in Si fo
r photoluminescence studies. Helium ions were implanted to form a dens
e subsurface layer of small cavities (1-16 nm diameter). Implanted spe
cimens subjected to annealing in a variety of atmospheres yielded no d
etectable photoluminescence. However, implantation combined with elect
rochemical anodization produced a substantial blueshift relative to an
odization alone. This blueshift is consistent with the quantum confine
ment model of photoluminescence in porous silicon. (C) American Instit
ute of Physics.