M. Eizenberg et al., TICN - A NEW CHEMICAL-VAPOR-DEPOSITED CONTACT BARRIER METALLIZATION FOR SUBMICRON DEVICES, Applied physics letters, 65(19), 1994, pp. 2416-2418
High-quality chemical vapor deposited TiCN films were produced in a si
ngle wafer reactor using a metallorganic (TDMAT) precursor. The films
have excellent step coverage over high aspect-ratio contacts as well a
s very low particle content. These properties are obtained because the
films are deposited under surface-reaction controlled conditions. The
films show also excellent barrier properties against Al and WF6 attac
k. These properties make this material a superb contact barrier materi
al for ultra-large-scale integrated devices. (C) 1994 American Institu
te of Physics.