Study of donor-type Si/SiO2 interfaces states shows that these centers
anneal at room temperature when neutral but are stable when charged p
ositively. Moreover, the anneal process is accompanied by the release
of H. We propose that the donor states are related to H attached to in
terfacial network sites, most likely O atoms, constituting electricall
y active complexes. When positively charged, H is strongly bonded; whe
n neutral H is only weakly attached. In the latter case it can escape
and dimerize so that the states disappear. Similar complexes tying dow
n H in a positively charged state would constitute small cross-section
hole traps in the bulk of the oxide. (C) 1994 American Institute of P
hysics.