BENZOTRIAZOLYLMETHYLAMINOSILANES - NOVEL AZOMETHINE YLIDE EQUIVALENTS

Citation
Ar. Katritzky et al., BENZOTRIAZOLYLMETHYLAMINOSILANES - NOVEL AZOMETHINE YLIDE EQUIVALENTS, Tetrahedron, 50(44), 1994, pp. 12571-12578
Citations number
44
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404020
Volume
50
Issue
44
Year of publication
1994
Pages
12571 - 12578
Database
ISI
SICI code
0040-4020(1994)50:44<12571:B-NAYE>2.0.ZU;2-Y
Abstract
Benzotriazolylmethylaminosilanes, readily accessible from the reaction of benzotriazole, an aldehyde and an (aminomethyl)silane in water at 20 degrees C, are azomethine ylide equivalents which undergo stereospe cific cycloadditions with dipolarophiles to give substituted pyrrolidi nes or 25-dihydropyrroles in good yields.