Saturn's giant moon Titan has a thick (1.5 bar) nitrogen atmosphere, w
hich has a temperature structure that is controlled by the absorption
of solar and thermal radiation by methane, hydrogen, and organic aeros
ols into which methane is irreversibly converted by photolysis. Previo
us studies of Titan's climate evolution have been done with the assump
tion that the methane abundance was maintained against photolytic depl
etion throughout Titan's history, either by continuous supply from the
interior or by buffering by a surface or near surface reservoir. Radi
ative-convective and radiative-saturated equilibrium models of Titan's
atmosphere show that methane depletion may have allowed Titan's atmos
phere to cool so that nitrogen, its main constituent, condenses onto t
he surface, collapsing Titan into a Triton-like frozen state with a th
in atmosphere.