COMPLEX-FORMATION OF PALLADIUM(II) WITH GERMANIUM(II) IN AQUEOUS-SOLUTIONS OF HCL

Citation
Pg. Antonov et al., COMPLEX-FORMATION OF PALLADIUM(II) WITH GERMANIUM(II) IN AQUEOUS-SOLUTIONS OF HCL, Russian journal of applied chemistry, 66(12), 1993, pp. 2030-2035
Citations number
12
Categorie Soggetti
Chemistry Applied
ISSN journal
10704272
Volume
66
Issue
12
Year of publication
1993
Part
1
Pages
2030 - 2035
Database
ISI
SICI code
1070-4272(1993)66:12<2030:COPWGI>2.0.ZU;2-L
Abstract
The process of complex formation of palladium(II) with germanium(II) i n solutions of 6 M HCl was studied. The positions of charge-transfer b ands in the UV spectra of Pd-Ge complexes were determined, the stabili ty of solutions over time was investigated, and some special kinetic f eatures of complex formation were clarified, The properties of the lig ands GeCla- in substitution reactions were studied. The composition an d structure of Pd-Ge complexes precipitated in a solid phase were dete rmined.