Pg. Antonov et al., COMPLEX-FORMATION OF PALLADIUM(II) WITH GERMANIUM(II) IN AQUEOUS-SOLUTIONS OF HCL, Russian journal of applied chemistry, 66(12), 1993, pp. 2030-2035
The process of complex formation of palladium(II) with germanium(II) i
n solutions of 6 M HCl was studied. The positions of charge-transfer b
ands in the UV spectra of Pd-Ge complexes were determined, the stabili
ty of solutions over time was investigated, and some special kinetic f
eatures of complex formation were clarified, The properties of the lig
ands GeCla- in substitution reactions were studied. The composition an
d structure of Pd-Ge complexes precipitated in a solid phase were dete
rmined.