COMPLEX-FORMATION AND STABILIZATION OF HIGHEST OXIDATION-STATES OF D-ELEMENTS IN SALT MELTS

Authors
KUZNETSOV SA STANGRIT PT
Citation
Sa. Kuznetsov et Pt. Stangrit, COMPLEX-FORMATION AND STABILIZATION OF HIGHEST OXIDATION-STATES OF D-ELEMENTS IN SALT MELTS, Russian journal of applied chemistry, 66(12), 1993, pp. 2036-2041
Citations number
27
Categorie Soggetti
Chemistry Applied
Journal title
Russian journal of applied chemistry → ACNP
ISSN journal
10704272
Volume
66
Issue
12
Year of publication
1993
Part
1
Pages
2036 - 2041
Database
ISI
SICI code
1070-4272(1993)66:12<2036:CASOHO>2.0.ZU;2-M
Abstract
Conditions of stabilization of highest oxidation states of 3d-5d-eleme nts in salt melts of various anionic and cationic compositions, which determine, respectively, the structure of the first and second coordin ation spheres of the complex, have been studied. The possibility of st abilization of higher oxidation states of the metal in the melts due t o the formation of heteronuclear complexes has been demonstrated.