AMIDES OF TRIVALENT PHOSPHORUS-ACIDS AS P HOSPHORYLATION MEANS FOR ALCOHOLS AND AMINES

Citation
Ee. Nifantev et Mk. Gratchev, AMIDES OF TRIVALENT PHOSPHORUS-ACIDS AS P HOSPHORYLATION MEANS FOR ALCOHOLS AND AMINES, Uspehi himii, 63(7), 1994, pp. 602-637
Citations number
580
Categorie Soggetti
Chemistry
Journal title
ISSN journal
00421308
Volume
63
Issue
7
Year of publication
1994
Pages
602 - 637
Database
ISI
SICI code
0042-1308(1994)63:7<602:AOTPAP>2.0.ZU;2-I
Abstract
The principal results of investigation of trivalent phosphorus acids a mides (TPAA) as phosphorylation means for alcohols, phenols and amines were summarized and discussed. The some problems of catalysis and mec hanism of phosphorylation of protonodonor nuckeophiles with using of T PAA were considered and new possibilities of works development in this direction were analyzed. The synthetic advantages of TPAA and concret e perspectives of their usage in the fine organic synthesis and marcro molecular chemistry were shown.