Experiments on the analysis of the wear debris produced during the pol
ishing of diamond and the rapid sliding of diamond upon diamond using
a high-speed sliding machine are presented. The debris was studied by
electron energy loss spectroscopy (EELS) in a scanning transmission el
ectron microscope (STEM) and by transmission electron microscopy (TEM)
. The aim of the work was to improve understanding of the polishing pr
ocess. It was found that the debris produced when polishing diamond in
a (100) direction on a (100) plane consisted of less dense forms of c
arbon. Diamond debris was instead found in the experiment with the hig
h-speed sliding machine, but the wear track showed markedly different
features from those observed on a surface after conventional polishing
. The results suggest that the polishing of diamond in the soft direct
ions occurs by a process in which diamond transforms to less dense for
ms of carbon, after which the transformed material detaches.