CHANGEOVER IN A MULTIMODAL COPPER(II) CATENATE AS MONITORED BY EPR SPECTROSCOPY

Authors
BAUMANN F LIVOREIL A KAIM W SAUVAGE JP
Citation
F. Baumann et al., CHANGEOVER IN A MULTIMODAL COPPER(II) CATENATE AS MONITORED BY EPR SPECTROSCOPY, Chemical communications, (1), 1997, pp. 35-36
Citations number
28
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
1
Year of publication
1997
Pages
35 - 36
Database
ISI
SICI code
1359-7345(1997):1<35:CIAMCC>2.0.ZU;2-4
Abstract
The electrochemically triggered rearrangement of a copper catenate is monitored by EPR spectroscopy;the initially generated tetrahedral copp er(II) complex (with higher g-factor components and lower metal hyperf ine splitting) is converted to a stable five-coordinate copper(II) spe cies, within a few minutes at room temperature, in anhydrous MeCN.