[FE3CU(SPRI)(6)CL-3](2-) - A NOVEL MIXED-METAL THIOLATE COMPLEX WITH A TRUNCATED ADAMANTANE-LIKE STRUCTURE

Authors
STEPHAN HO HENKEL G KANATZIDIS MG
Citation
Ho. Stephan et al., [FE3CU(SPRI)(6)CL-3](2-) - A NOVEL MIXED-METAL THIOLATE COMPLEX WITH A TRUNCATED ADAMANTANE-LIKE STRUCTURE, Chemical communications, (1), 1997, pp. 67-68
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
1
Year of publication
1997
Pages
67 - 68
Database
ISI
SICI code
1359-7345(1997):1<67:[-ANMT>2.0.ZU;2-Z
Abstract
Reaction of [Fe-2(SPri)(6)](2-) with FeCl2 and CuCl in a 1:1:1 molar r atio in hot tetrahydrofuran gives the complex anion [Fe3Cu(SPri)(6)Cl- 3](2-) which contains a Fe3Cu pyramidal core; the structure, magnetic properties and the solution H-1 NMR spectrum are reported.