PREPARATION OF TUNABLE (PH(2)P(CH2)(N)PPH2)RU(2-METHYLPROPENYL)(2) CATALYSTS AND THEIR USE FOR THE STEREOSELECTIVE SYNTHESIS OF DIENYL ESTERS

Authors
DOUCET H HOFER J DERRIEN N BRUNEAU C DIXNEUF PH
Citation
H. Doucet et al., PREPARATION OF TUNABLE (PH(2)P(CH2)(N)PPH2)RU(2-METHYLPROPENYL)(2) CATALYSTS AND THEIR USE FOR THE STEREOSELECTIVE SYNTHESIS OF DIENYL ESTERS, Bulletin de la Societe chimique de France, 133(10), 1996, pp. 939-944
Citations number
37
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology,Chemistry
Journal title
Bulletin de la Societe chimique de France → ACNP
ISSN journal
00378968
Volume
133
Issue
10
Year of publication
1996
Pages
939 - 944
Database
ISI
SICI code
0037-8968(1996)133:10<939:POT(C>2.0.ZU;2-F
Abstract
New (Ph(2)P(CH2)(n)PPh(2))Ru(2-methylpropenyl) 2 complexes have been p repared and their catalytic activity chas made possible the regioselec tive anti-Markovnikov and stereoselective trans-addition of carboxylic acids to enynes and the straightforward access to (Z)-alka-1,3-dien-1 -yl esters.